Page 121 - 《摩擦学学报》2021年第2期
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266 摩 擦 学 学 报 第 41 卷
16 000 5 000
(a) 531.3 ev B 4 800 (b) P-2p B
14 000 4 600
Intensity/a.u. 10 000 Intensity/a.u. 4 400
12 000
4 200
4 000
8 000
3 800
6 000 3 600
3 400
4 000 3 200
525 530 535 130 132 134 136
4 400
530.3 ev 531.92 ev A 4 200 A
6 000 4 000
Intensity/a.u. 5 000 Intensity/a.u. 3 800 P-2p
3 600
3 400
3 200
3 000
4 000
525 530 535 130 132 134 136
Binding energy/keV Binding energy/keV
90 000 (c) 932.9 eV B 45000 (d) 1 022.05 eV B
80 000
40000
Intensity/a.u. 60 000 933 eV Intensity/a.u. 35000
70 000
50 000
30000
40 000
25000
30 000
20 000
10 000 20000
15000
930 932 934 936 1 020 1 025
90 000 A 35000 A
Intensity/a.u. 70 000 932.9 eV 933.2 eV Intensity/a.u. 30000 1 022.5 eV 1 021.48 eV
80 000
60 000
50 000
25000
40 000
30 000
20 000
15000
10 000 20000
930 932 934 936 1 020 1 025
Binding energy/keV Binding energy/keV
Fig. 10 XPS narrow scans of the copper alloy surface after tribological test;O1s (a),P2p(b) Cu2p3(c),Zn2p3 (d) components inside
the wear track lubricated by drawing fluids A and B
图 10 拉丝液A和B的磨痕区XPS的O1s(a)、P2p(b)、Cu2p3(c)、Zn2p3(d)窄谱对比图
了有利于橡胶与黄铜结合的氧化亚铜等物质,这些物 [ 1 ] Luo Jianbin. Fuzzy problems in plastic metal working[J]. Gangtie,
质有利于橡胶与黄铜的硫化,使其结合更牢固. 同时 1992, 27(3): 76–80 (in Chinese) [雒建斌. 金属塑性加工领域中的
表面相对粗糙的微观形貌也增加了钢帘线与橡胶的 模糊问题[J]. 钢铁, 1992, 27(3): 76–80]. doi: 10.13228/j.boyuan.issn
0449-749x.1992.03.018.
附着力.
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3 结论 drawing strain on the fatigue behavior of tire cord filaments[J].
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a. 钢帘线拉拔过程中出现断丝的情况与拉拔液 2018, 21(3): 289–296. doi: 10.1016/j.jestch.2018.04.010.
的润滑性能相关. [ 3 ] Kruzel R, Ulewicz M. Analysis of fatigue life of the steel cord used
b. 在摩擦过程中,拉拔液的添加剂与黄铜发生摩 in tires in unidirectional and bidirectional bending[J]. Procedia
擦化学反应,摩擦后在黄铜表面生产较厚的氧化层, Structural Integrity, 2018, 13: 1626–1631. doi: 10.1016/j.prostr.
2018.12.342.
同时生成1层磷化合物的反应膜,从而在拉拔过程中
[ 4 ] Radionova L V, Shirokov V V, Faizov S R, et al. Studies of
起到了抗磨减磨的作用.
influence of process parameters on the strain rate at high-speed wire
c. 拉拔液与钢帘线镀层中铜、锌元素的反应产物
drawing[J]. Materials Science Forum, 2019, 946: 832–838. doi:
以及铜、锌元素的氧化程度对钢帘线后续工序产生较 10.4028/www.scientific.net/msf.946.832.
大影响. 当镀层表层形成Zn-OH及反应物时,将会对 [ 5 ] Hollinger S, Depraetere E, Giroux O. Wear mechanism of tungsten
钢帘线与橡胶的粘合性产生不利影响. carbide dies during wet drawing of steel tyre cords[J]. Wear, 2003,
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参 考 文 献
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