Page 11 - 《摩擦学学报》2020年第6期
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694                                     摩   擦   学   学   报                                 第 40 卷


                   30 000                                             6 800
                         (a)                                                (b)       Experiment Cr 2p
                                                                      6 600           Envolope
                   28 000
                                                                                      Background
                                                                      6 400           Cr 2 O 3
                 Intensity/a.u.  24 000                              Intensity/a.u.  6 200
                   26 000
                                                                                      NiCr 2 O 4
                                                                      6 000
                            Envolope
                   22 000   Experiment Ni 2p                          5 800
                            Background
                            NiO                                       5 600
                   20 000
                            NiCr 2 O 4
                                                                      5 400
                        884 880 876 872 868 864  860  856 852             592  588   584   580   576   572
                                Binding energy/eV                                  Binding energy/eV
                   21 000                                             3 200
                         (c)             Experiment Ba 3d                      Experiment Ag 3d      (d)
                                         Envolope                     3 150    Envolope
                                         Background                            Background
                   20 000
                                         BaMoO 4                      3 100    Ag
                 Intensity/a.u.  19 000                              Intensity/a.u.  3 050
                                                                               AgO
                                                                      3 000
                   18 000                                             2 950
                                                                      2 900
                   17 000                                             2 850
                      783       780       777       774                   380 378 376 374 372 370 368 366 364
                                Binding energy/eV                                  Binding energy/eV
                   14 000                                             30 000
                         (e)       Experiment Fe 2p                         (f)
                                   Envolope                           28 000
                                   Background
                   13 000
                                   Fe 3 O 4                           26 000
                 Intensity/a.u.  12 000                             Intensity/a.u.  24 000
                                                                               Envolope
                   11 000                                             22 000   Experiment Ni 2p
                                                                               Background
                                                                               NiO
                                                                      20 000
                                                                               NiCr 2 O 4
                   10 000
                      730   725   720   715   710   705                    884 880 876 872 868 864  860  856 852
                                Binding energy/eV                                  Binding energy/eV
                   7 200                                              20 400
                         (g)       Experiment Cr 2p                           Experiment Ba 3d       (h)
                   7 000           Envolope                           20 000  Envolope
                                   Background                                 Background
                   6 800
                                   NiCr 2 O 4                         19 600  BaMoO 4
                  Intensity/a.u.  6 400                             Intensity/a.u.  19 400
                   6 600
                                   Cr 2 O 3
                                                                      19 200
                   6 200
                   6 000                                              18 800
                   5 800                                              18 400
                   5 600                                              18 000
                       592  588   584   580   576   572                       782     780      778     776
                                Binding energy/eV                                  Binding energy/eV
                                            3 000
                                                    Experiment Ag 3d       (i)
                                                    Envolope
                                            2 950   Background
                                                    Ag
                                           Intensity/a.u.  2 900
                                                    AgO
                                            2 850

                                            2 800
                                            2 750
                                               380 378 376 374 372 370 368 366 364
                                                         Binding energy/eV

                         Fig. 9  The fitted XPS spectra of the wear surfaces at 800 ℃:(a~e) Ni 3 Al/316L;(f~i) Ni 3 Al/Al 2 O 3
                                 图 9    800 ℃时磨损表面XPS拟合谱:(a~e) Ni 3 Al/316L;(f~i) Ni 3 Al/Al 2 O 3
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