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第 5 期              秦晨曦, 等: 基于主客体相互作用的水下自适应仿生胶黏剂的设计及性能研究                                      731



                           1 000
                                      Our work



                            800     Advanced Functional Materials, 2022, 32(44): 2205597.


                                                                       Materials Horizons, 2020, 7(1): 282-288.
                           Adhesion strength/kPa  Joural of Materials Chemistry A, 2021, 9(22): 12988-13000.  SmartMat, 2024, 5(2): e1235.
                            600
                                             ACS Applied Materials & Interfaces, 2023, 15(27): 32863-32874.



                            400
                                        Advanced Materials, 2019, 31(49): 1905761.  Advanced Functional Materials,
                                                                             2024, 34(3): 2308790.
                                          Advanced Science, 2024, 11: 2308538.
                            200

                                 Chemical Engineering Joumal, 2024, 480: 148064.
                             0

                                       Fig. 6    Compared with the reported underwater adhesives
                                             图 6    与现有报道的水下胶黏剂进行对比

                180                                              800

                    (a)                   pH 3.2                    (b)
                                          pH 6.5
                135                       pH 9.3                 600
                                          pH 11.8
               Force/N  90                                      Adhesion strength/kPa  400


                45                                               200


                 0                                                0
                  0.0    0.5    1.0     1.5    2.0                   pH 3.2  pH 6.5  pH 9.3  pH 11.8
                           Displacement/mm                                     pH value
                160
                    (c)                   Steel     1000  (d)
                                          Ti
               Force/N 120                Al         800
                 80
                                          Copper
                                          Brass
                 40
                 0                     PET          Adhesion strength/kPa  600
                                       PI
               Force/N 114             Carbon fiber  400
                                       PMMA
                 76
                                       PC
                                                     200
                                       PVC
                 38
                 0                                    0
                  0.0    0.5    1.0     1.5    2.0      Steel  Ti  Al Copper Brass PET  PI  Carbon PMMA PC  PVC
                           Displacement/mm                                               fiber
                                                                                 Substrate
             Fig. 7    (a) Adhesion curve of P3-adhesive to steel sheets after soaking in different pH media for 12 h; (b) Adhesion strength of P3-
                   adhesive to steel sheets after soaking in different pH media for 12 h; (c) Adhesion curve of P3-adhesive to different
                       substrates after soaking in artificial seawater for 12 h; (d) Adhesion strength of P3-adhesive to different
                                         substrates after soaking in artificial seawater for 12 h
                 图 7    (a) P3胶黏剂在不同pH介质中浸泡12 h后在钢片上的黏附曲线;(b) P3胶黏剂在不同pH介质中浸泡12 h后在
                            钢片上的黏附强度;(c) P3胶黏剂在人工海水中浸泡12 h后在不同基材上的黏附曲线;
                                    (d) P3胶黏剂在人工海水中浸泡12 h后在不同基材上的黏附强度
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