Page 69 - 《爆炸与冲击》2026年第2期

第 46 卷 葛 雨，等： 掺氨量对管道氨气-氢气-空气预混气体爆燃特性的影响 第 2 期

(2) 随着掺氨量的升高，火焰传播速度以及超压均有不同程度的下降，达到超压峰值的时间延长，最
大掺氨量（φ=85%）到达超压峰值所用时间是最小掺氨量（φ=35%）所用时间的 2.06 倍。
(3) 不同掺氨量压力时程曲线均呈现三峰结构，与其他文献结果一致。随着 φ 的上升，3 种峰值有不
同程度的降低，其中 p 降低幅度最大，降幅达到 84.18%。氨气含量的上升可以很好地抑制氢气爆炸危
3
害性。

参考文献：

[1] VALERA-MEDINA A, XIAO H, OWEN-JONES M, et al. Ammonia for power [J]. Progress in Energy and Combustion
Science, 2018, 69: 63–102. DOI: 10.1016/j.pecs.2018.07.001.
[2] ORUC O, DINCER I. Assessing the potential of thermo-chemical water splitting cycles: a bridge towards clean and
sustainable hydrogen generation [J]. Fuel, 2021, 286: 119325. DOI: 10.1016/j.fuel.2020.119325.
[3] ISLAM A, ISLAM T, MAHMUD H, et al. Accelerating the green hydrogen revolution: a comprehensive analysis of
technological advancements and policy interventions [J]. International Journal of Hydrogen Energy, 2024, 67: 458–486. DOI:
10.1016/j.ijhydene.2024.04.142.
[4] AZIZ M, JUANGSA F B, IRHAMNA A R, et al. Ammonia utilization technology for thermal power generation: a review [J].
Journal of the Energy Institute, 2023, 111: 101365. DOI: 10.1016/j.joei.2023.101365.
[5] WU Z J, YU Y, XIE W, et al. Optimization of the flame characteristics of H 2 -O 2 coaxial injection applied to hydrogen-fueled
argon cycle engines [J]. International Journal of Hydrogen Energy, 2021, 46(27): 14780–14789. DOI: 10.1016/j.ijhydene.
2021.01.197.
[6] VAN DEN SCHOOR F, VERPLAETSEN F, BERGHMANS J. Calculation of the upper flammability limit of methane/
hydrogen/air mixtures at elevated pressures and temperatures [J]. International Journal of Hydrogen Energy, 2008, 33(4):
1399–1406. DOI: 10.1016/j.ijhydene.2008.01.002.
[7] SU B, DONG H W, LUO Z M, et al. Effects of H 2 /CO ratio and CO 2 dilution on the explosion behavior and flame evolution of
syngas/air mixtures [J]. International Journal of Hydrogen Energy, 2024, 69: 451–465. DOI: 10.1016/j.ijhydene.2024.04.360.
[8] ICHIKAWA Y, OTAWARA Y, KOBAYASHI H, et al. Flame structure and radiation characteristics of CO/H 2 /CO 2 /air
turbulent premixed flames at high pressure [J]. Proceedings of the Combustion Institute, 2011, 33(1): 1543–1550. DOI:
10.1016/j.proci.2010.05.068.
[9] LEE M C, YOON J, JOO S, et al. Gas turbine combustion characteristics of H 2 /CO synthetic gas for coal integrated
gasification combined cycle applications [J]. International Journal of Hydrogen Energy, 2015, 40(34): 11032–11045. DOI:
10.1016/j.ijhydene.2015.06.086.
[10] WANG L, JIANG Y, PAN L W, et al. Lagrangian investigation and chemical explosive mode analysis of extinction and re-
ignition in H 2 /CO/N 2 syngas non-premixed flame [J]. International Journal of Hydrogen Energy, 2016, 41(8): 4820–4830.
DOI: 10.1016/j.ijhydene.2016.01.043.
[11] SU B, LUO Z M, KRIETSCH A, et al. Quantitative investigation of explosion behavior and spectral radiant characteristics of
free radicals for syngas/air mixtures [J]. International Journal of Hydrogen Energy, 2024, 50: 1359–1368. DOI: 10.1016/j.
ijhydene.2023.10.280.
[12] KOJIMA Y, YAMAGUCHI M. Ammonia as a hydrogen energy carrier [J]. International Journal of Hydrogen Energy, 2022,
47(54): 22832–22839. DOI: 10.1016/j.ijhydene.2022.05.096.
[13] SUN S C, JIANG Q Q, ZHAO D Y, et al. Ammonia as hydrogen carrier: advances in ammonia decomposition catalysts for
promising hydrogen production [J]. Renewable and Sustainable Energy Reviews, 2022, 169: 112918. DOI: 10.1016/j.rser.
2022.112918.
[14] LAMB K E, DOLAN M D, KENNEDY D F. Ammonia for hydrogen storage; a review of catalytic ammonia decomposition
and hydrogen separation and purification [J]. International Journal of Hydrogen Energy, 2019, 44(7): 3580–3593. DOI:
10.1016/j.ijhydene.2018.12.024.
[15] YU Z, ZHANG H W. End-gas autoignition and knocking combustion of ammonia/hydrogen/air mixtures in a confined reactor [J].
International Journal of Hydrogen Energy, 2022, 47(13): 8585–8602. DOI: 10.1016/j.ijhydene.2021.12.181.

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