Page 41 - 摩擦学学报2025年第9期

第 45 卷 第 9 期 摩擦学学报（中英文） Vol 45 No 9
2025 年 9 月 Tribology Sept, 2025

DOI: 10.16078/j.tribology.2024095 CSTR: 32261.14.j.tribology.2024095
刘瑞文, 张晓, 鲁艳, 王琮, 玄翠娟, 郝俊英, 于专妮. 微织构F-DLC涂层表面润湿与摩擦学性能研究[J]. 摩擦学学报（中英文）,
2025, 45(9): 1295−1304. LIU Ruiwen, ZHANG Xiao, LU Yan, WANG Cong, XUAN Cuijuan, HAO Junying, YU Zhuanni.
Wettability and Tribological Performances of the Textured F-DLC Coating Surface[J]. Tribology, 2025, 45(9): 1295−1304.

微织构F-DLC涂层表面润湿与摩擦学性能研究

2,3
1
2,3
1
2*
2
刘瑞文 , 张 晓 , 鲁 艳 , 王 琮 , 玄翠娟 , 郝俊英 , 于专妮 1*
(1. 青岛农业大学 化学与药学院，山东 青岛 266109；
2. 中国科学院 兰州化学物理研究所 润滑材料全国重点实验室，甘肃 兰州 730000；
3. 青岛市资源化学与新材料研究中心，山东 青岛 266000)
摘 要: 采用激光织构技术对304不锈钢表面进行微织构处理，并利用等离子体增强化学气相沉积(PECVD)工艺在
其表面制备氟掺杂类金刚石(F-DLC)涂层，构建疏水表面，研究了微织构处理和F-DLC涂层对304不锈钢表面润湿
性和摩擦学性能的影响. 结果表明：氟元素掺杂可以降低类金刚石碳(DLC)涂层的表面能，使得304不锈钢表面的静
态水接触角由57°提高至107°，实现由亲水性表面到疏水性表面的转变；而在沉积涂层之前进行激光织构，激光织构
的图案和织构过程中激光烧蚀形成的纳米小颗粒在沉积涂层后形成的团簇结构，使得接触角达到144°；通过设计
不同微织构图案，可实现对涂层摩擦学性能的调控，其中以0.1 mm (间距)× 0.1 mm (直径)激光点阵处理的F-DLC织
构涂层具有最优的摩擦学性能，圆孔型织构形成的凹坑可以储存摩擦磨损产生的磨屑，从而降低涂层的摩擦系数，
使涂层的稳定摩擦系数仅为0.2. 因此，通过优化激光点阵结构进行微织构处理，结合氟掺杂DLC涂层技术，可以显
著提高304不锈钢表面的疏水性能和摩擦学性能.
关键词: 疏水表面; F-DLC涂层; 表面微织构; 摩擦学性能; 润湿性能
中图分类号: TH117.1 文献标志码: A 文章编号: 1004-0595(2025)09–1295–10

Wettability and Tribological Performances of the

Textured F-DLC Coating Surface

1 2,3 2,3 2 1 2* 1*
LIU Ruiwen , ZHANG Xiao , LU Yan , WANG Cong , XUAN Cuijuan , HAO Junying , YU Zhuanni

(1. College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University,
Shandong Qingdao 266109, China;
2. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics,
Chinese Academy of Sciences, Gansu Lanzhou 730000, China;
3. Qingdao Center of Resource Chemistry and New Materials, Shandong Qingdao 266000, China)
Abstract: At low temperatures, the surface of the substrate is prone to freezing, resulting in losses. With the
development of nanotechnology and biomimetic technology, hydrophobic surfaces are widely used in the field of surface
frosting/ice protection. The hydrophobic surface can greatly inhibit the penetration and adhesion of liquid on the surface
to achieve the effect of anti-icing, which is mainly affected by the surface micro-nano structure and low surface energy.
At the same time, the durability of hydrophobic coatings in low-temperature and high-humidity environments is crucial.

Received 7 May 2024, revised 10 July 2024, accepted 11 July 2024, available online 30 September 2024.
*Corresponding author. E-mail: jyhao@licp.cas.cn, Tel: +86-931-4968236; E-mail: 200301110@qau.edu.cn, Tel: +86-15092297679.
This project was supported by the Basic Research Project (2020-JCJQ-ZD-155-20), PhD Fund of Qingdao Agricultural University
(1119016) and Major Science and Technology Project of Gansu Province (23ZDGA011).
基础研究项目(2020-JCJQ-ZD-155-20)、青岛农业大学博士启动项目(1119016)和甘肃省重大专项(23ZDGA011)资助.