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第 45 卷 第 8 期 摩擦学学报（中英文） Vol 45 No 8
2025 年 8 月 Tribology Aug, 2025
DOI: 10.16078/j.tribology.2024123 CSTR: 32261.14.j.tribology.2024123
孟维晟, 刘小龙, 王海忠, 乔旦, 冯大鹏, 宋增红, 张坚, 韩峰. 遥爪型全氟聚醚自组装膜的表面性能及抗磨损和抗腐蚀性能研究[J].
摩擦学学报（中英文）, 2025, 45(8): 1140−1150. MENG Weisheng, LIU Xiaolong, WANG Haizhong, QIAO Dan, FENG Dapeng,
SONG Zenghong, ZHANG Jian, HAN Feng. Surface Properties, Wear Resistance, and Corrosion Resistance of Telechelic
Perfluoropolyethers Self-assembled Films[J]. Tribology, 2025, 45(8): 1140−1150.
遥爪型全氟聚醚自组装膜的表面性能及
抗磨损和抗腐蚀性能研究
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1
孟维晟 , 刘小龙 , 王海忠 , 乔 旦 , 冯大鹏 , 宋增红 , 张 坚 , 韩 峰 3
2
2
1*
1*
1
(1. 中国科学院兰州化学物理研究所 固体润滑国家重点实验室，甘肃 兰州 730000；
2. 山东东岳高分子材料有限公司 含氟功能膜材料国家重点实验室，山东 淄博 256401；
3. 山东农业大学 化学与材料科学院，山东 泰安 271000)
摘 要: 本文中以双端羧基Z型全氟聚醚为原料，经还原和三甲氧基氯硅烷取代合成了具有双端硅氧烷基的两亲性
Z型遥爪型全氟聚醚(PFSi, M n ≈10000)，通过自组装，将PFSi锚定于羟基化的硅片及铜片表面，形成相应的膜. 考察
了自组装膜的表面性能和耐磨损性能，并探究了遥爪型全氟聚醚膜的抗腐蚀性能. 结果表明：PFSi自组装膜表现出
较好的表面性能(表面张力<10 mN/m). 同时，经扫描电子显微镜观察，硅片表面的自组装膜为多层结构. 加速磨损
试验和电化学腐蚀试验表明：PFSi表现出优异的耐磨性能和耐腐蚀性能. 本工作中在制备具有耐磨损和耐腐蚀能力
的低表面能膜的基础上，研究了两亲性遥爪型聚合物在固体表面的自组装行为，这将为设计可控自组装功能的含
氟聚合物开辟1条新途径.
关键词: 全氟聚醚; 硅氧烷; 遥爪型聚合物; 多层结构; 自组装
中图分类号: TH117.1 文献标志码: A 文章编号: 1004-0595(2025)08–1140–11
Surface Properties, Wear Resistance, and Corrosion Resistance
of Telechelic Perfluoropolyethers Self-assembled Films
1
1*
1
1
1*
MENG Weisheng , LIU Xiaolong , WANG Haizhong , QIAO Dan , FENG Dapeng ,
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SONG Zenghong , ZHANG Jian , HAN Feng 3
(1. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of
Sciences, Gansu Lanzhou 730000, China;
2. State Key Laboratory of Fluoride-Containing Functional Membrane Materials, Shandong
Dongyue Polymer Materials Co, LTD, Shandong Zibo 256401, China;
3. School of Chemistry and Materials Science, Shandong Agricultural University, Shandong Tai’an 271000, China)
Abstract: In recent years, with the continuous acceleration of industrialization and urbanization, various equipment
surfaces are frequently exposed to harsh environments and pollution sources, leading to an increasing demand for
antifouling and corrosion resistance of material surfaces. As the complexity of demands and environments grows,
traditional protective coating materials gradually prove inadequate. Therefore, it was highly significant to develop
Received 14 June 2024, revised 25 August 2024, accepted 26 August 2024, available online 2 January 2025.
*Corresponding author. E-mail: whzhlsl@licp.cas.cn, Tel: +86-931-4968170; E-mail: dpfeng@licp.cas.cn, Tel: +86-931-4968075.
This project was supported by the Shandong Natural Science Foundation Fluorosilicate Materials Mutual Fund (ZR2019LFG001,
ZR2019LFG002, ZR2019LFG009).
山东省自然科学基金氟硅材料联合基金项目(ZR2019LFG001, ZR2019LFG002, ZR2019LFG009)资助.
