Page 4 - 摩擦学学报2025年第10期

第 45 卷 第 10 期 摩擦学学报（中英文） Vol 45 No 10
2025 年 10 月 Tribology Oct, 2025

DOI: 10.16078/j.tribology.2024191 CSTR: 32261.14.j.tribology.2024191
陈加丽, 刘晓玲, 裴孝虎, 王浩成, 张松伟, 郭峰. 伯仲叔铵盐对质子型离子液体添加剂润滑性能的影响[J]. 摩擦学学报（中英
文 ） , 2025, 45(10): 1401−1416. CHEN Jiali, LIU Xiaoling, PEI Xiaohu, WANG Haocheng, ZHANG Songwei, GUO Feng.
Primary Secondary Tertiary Ammonium Salt on Lubrication Properties of Protic Ionic Liquid Additives[J]. Tribology, 2025, 45(10):
1401−1416.

伯仲叔铵盐对质子型离子液体

添加剂润滑性能的影响

1
1*
2,3
1
1,2
陈加丽 , 刘晓玲 , 裴孝虎 , 王浩成 , 张松伟 , 郭 峰 1
(1. 青岛理工大学 机械与汽车工程学院，山东 青岛 266520；
2. 中国科学院 兰州化学物理研究所 固体润滑国家重点实验室，甘肃 兰州 730000；
3. 青岛市资源化学与新材料研究中心，山东 青岛 266071)
摘 要: 选择具有相同阴离子和链长的伯仲叔铵盐离子液体(N 1 P、N 2 P和N 3 P)作为聚α烯烃基础油(PAO10)的添加
剂，通过试验探究伯仲叔离子液体的润滑性能差异. 采用UMT摩擦磨损试验机从添加浓度和摩擦频率方面探究其
减摩抗磨性能；使用共聚焦显微镜测量磨损量、SEM扫描电子显微镜观察磨痕、EDS能谱仪和X射线光电子能谱(XPS)
分析摩擦表面化学元素；使用光干涉润滑油膜试验台探究3种质子型离子液体的成膜性能. 结果发现同等条件下伯
铵盐离子液体油样减摩抗磨性能和成膜性能最好. 且通过吸附膜表征试验证实离子液体会在摩擦表面形成吸附
层，起到表面改性作用，同样是伯铵盐离子液体油样形成吸附层最厚.
关键词: 离子液体添加剂; 质子型离子液体; 摩擦性能; 成膜性能; 阳离子碳链
中图分类号: TH117.2 文献标志码: A 文章编号: 1004-0595(2025)10–1401–16

Primary Secondary Tertiary Ammonium Salt on Lubrication

Properties of Protic Ionic Liquid Additives

1 1* 1 1,2 2,3 1
CHEN Jiali , LIU Xiaoling , PEI Xiaohu , WANG Haocheng , ZHANG Songwei , GUO Feng
(1. School of Mechanical and Automotive Engineering, Qingdao University of Technology,
Shandong Qingdao 266520, China;
2. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics,
Chinese Academy of Sciences, Gansu Lanzhou 730000, China;
3. Qingdao Center of Resource Chemistry & New Materials, Shandong Qingdao 266071, China)
Abstract: In order to investigate the influence of the number of cationic carbon chains on the tribological properties of
ionic liquids, three protone-type ionic liquids with the same anion and chain length, N 1 P(N8HHH[DEHP]),
N 2 P(N88HH[DEHP]) and N 3 P(N888H[DEHP]), were selected as additives to the polyA olefinic base oil (PAO10), and
the differences in lubrication properties of the liquid were investigated by experiments. The UMT friction and wear
testing machine was used to investigate its anti-friction and anti-wear performance in terms of addition concentration and
friction frequency. The wear amount was measured by confocal microscope, the wear marks were observed by SEM

Received 31 August 2024, revised 7 November 2024, accepted 11 November 2024, available online 25 February 2025.
*Corresponding author. E-mail: LXL@qut.edu.cn, Tel: +86-13678850151.
This project was supported by the National Natural Science Foundation of China (52375190, 51475250), and the Taishan Scholars
Talent Project (TS20190943).
国家自然科学基金项目(52375190, 51475250)和泰山学者人才工程项目(TS20190943)资助.